a. PBr3(l) + 3H20(l) H3P03(aq) + 3HBr (aq) No reciox b. Nal (aq) 3HOCl (aq) + Na O (aq) 3HCl (aq) CI reduced c. 3S02 (g) 2HN03 (aq) + 2H20 (l) 3H2S04(aq) 2NO (g) (Il) S YIU) reduced If they do, identify the elements that undergo changes in oxidation number. Lets do PBr3 above. The oxidation number of most Group 16 elements is -2. If they do, identify the elements that undergochanges in oxidation number. Bonds between atoms of the same element (homonuclear bonds) are always divided equally. The answer will be a number for each atom with an associated sign. 1. Since it is neutral the total=0. Indicate whether the following balanced equatins involve oxidation-reduction. The invention relates to a process for the direct preparation of high purity PBr3 which consists in reacting HBr gas with a weight content of bromine equal to or less than 10 ppm on PCl3, in the absence of diluent or solvent , with an HBr / PCl3 molar ratio ranging from 3 to 5, at a temperature between 10degreC and 40degreC. Indicate whether the following balanced equations involve oxidation-reduction. ; When oxygen is part of a peroxide, its oxidation number is -1. + 5 0(g) 12(s) + 5 C 2(g) I from +5 to 0 C from +2 to +4 2+ + 2 Hg(l) + + 4 Hg from +2 to 0 + 2 (aq) The oxidation number of oxygen in compounds is usually -2. (a) PBr3(l) + 3 H2O(l) → H3PO3(aq) + 3 HBr(aq) (b) NaI(aq) + 3 HOCl(aq) → NaIO3(aq) + 3 HCl(aq) (c) 3 SO2(g) + 2 HNO3(aq) + 2 H2O(l) → 3 H2SO4(aq) + 2 NO(g) Assign an oxidation number of -2 to oxygen (with exceptions). The oxidation number of a Group 1 element in a compound is +1. +3 for P -1 for Br 5. Not available. (a) PBr3(l) + 3 H2O(l) → H3PO3(aq) + 3 HBr(aq) (b) 3 SO2(g) + 2 HNO3(aq) + 2 H2O(l) → 3 H2SO4(aq) + 2 NO(g) 6. Different ways of displaying oxidation numbers of ethanol and acetic acid. The oxidation number of each atom can be calculated by subtracting the sum of lone pairs and electrons it gains from bonds from the number of valence electrons. There are a few exceptions to this rule: When oxygen is in its elemental state (O 2), its oxidation number is 0, as is the case for all elemental atoms. 4. Br has -1. SO +1, -2 etc. Rules to remember… Exception: In hydrides, the oxidation number of hydrogen is -1, as in CaH 2. In each of the following balanced oxidation-reduction equations, identify those elements that undergo changes in oxidation number and indicate the magnitude of the change. If they do, identify the elements that undergo changes in oxidation number. The oxidation number is the number of electrons each atom donates or accepts when forming the compound. 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